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51.
Yong-Hoon Kim Md. Mashiur Rahman Zhen-Long Zhang Nobuo Misawa Ryugo Tero Tsuneo Urisu 《Chemical physics letters》2006,420(4-6):569-573
The effect of the electrostatic attractive force between giant unilamellar vesicles (GUVs) and the SiO2 surface on the formation of a Ca2+-free supported lipid bilayer (SLB) was investigated by atomic force microscopy and fluorescence microscopy. When negatively charged GUVs were incubated for 1 h without Ca2+, the surface coverage of lipid bilayer was <1% on the SiO2 surface. In contrast, a high coverage was obtained without addition of Ca2+ on the positively charged surface modified by aminopropyldimethylethoxysilane, and the coverage of SLBs decreased with increasing KCl concentrations. The thickness of the water layer under SLB was reduced by modification of APS. 相似文献
52.
Nobukatsu Nemoto Hiroji Ishii Manabu Ihara Nobuo Takamiya Koji Ikeda 《Journal of polymer science. Part A, Polymer chemistry》1994,32(13):2457-2467
The oxidation of hydroquinone catalyzed by pyridine-Cu(II) complexes attached to polyorganosiloxane was investigated in the mixed solvent of methanol/water (vol. ratio 2/1). The catalytic oxidation followed Michaelis-Menten-like kinetics. The large k2 term related to a turnover number indicated that the present polymeric catalysts have a remarkable effect on the activation process. The methylene number between the side-chain acid amido and pyridyl groups of the polymeric ligand was shown to be closely related to the appearance of hydrophobic effects in both the substrate-binding and the activation processes as deduced from the Michaelis constant and the thermodynamic and activation parameters. The binding parameters for 4-methoxyphenol with pyridyl-functionalized polyorganosiloxanes supported that the flexible backbone is also effective in the oxidation of hydroquinone. The Cu(II) complexes with pyridyl-functionalized polyorganosiloxane would have the structures distorted from square planar formation, which would promote the reduction of Cu(II) to Cu(I), as concluded from ESR spectroscopy and electrochemical measurement. © 1994 John Wiley & Sons, Inc. 相似文献
53.
54.
Nobuo Inagaki 《Annals of the Institute of Statistical Mathematics》1994,46(4):633-640
The maximal operator plays the similar role as the summation operator in the sense of stability of operation. So, we could discussARMA processes in the maximal operation by the same way as in the summation operation. However, many papers already treated with moving order statistics. In this paper, we discuss asymptotic behaviors of maximal autoregressive (MAR) processes with the weight tending to 1. 相似文献
55.
Highly efficient processes for fine particle formation of metal alloys and metal oxides were developed using a high-power laser. In these processes, laser light was used only for the ignition of a thermal chain reaction. This reaction was suppressed by adding inert gases, and the suppression effect was in the order C3H8 > C2H6 > CH4 > He > Ar > Xe. Oxygen accelerated the reaction because of the large exothermicity of the reaction of oxygen with methyl metal compounds. 相似文献
56.
Nobuo Aoki 《Topology and its Applications》1985,20(1):1-15
It is proved, by using topological properties, that when a group automorphism of a locally compact totally disconnected group is ergodic under the Haar measure, the group is compact. The result is an answer for Halmos's question that has remained open for the totally disconnected case. 相似文献
57.
Nobuo Inagaki Pranab Kumar Sen 《Annals of the Institute of Statistical Mathematics》1985,37(1):251-269
Summary The basic regularity conditions pertaining to the asymptotic theory of progressively truncated likelihood functions and maximum
likelihood estimators are considered, and the uniform strong consistency and weak convergence of progressively truncated maximum
likelihood estimators are studied systematically.
Work done during the first author's visit (as a visiting scholar) to the University of North Carolina at Chapel Hill, supported
by the Ministry of Education of the Japanese Government.
Work supported by the (U.S.) National Heart, Lung and Blood Institute, Contact NIH-NHLBI-F1-2243-L. 相似文献
58.
Nobuo Yoshida 《Chemical physics letters》1982,88(4):413-418
The assumptions usually made that the ionic atmosphere has spherical symmetry in the diffusion of binary electrolytes and that the electrophoretic effect is negligible in the tracer diffusion of ions are pointed out to be incorrect when terms up to order κ2 ln κ (κ is the Debye-Hückel parameter) are considered. 相似文献
59.
(1,5-Cyclooctadiene) (4-substituted pyridinium 2-pyridylcarbonylmethylide)- rhodium(I) perchlorates, [Rh(COD)(C5H4NC(O)C?H+C5H4X-4)]ClO4 [COD = 1,5-cyclooctadiene; X = CH3C(O), CH3OC(O), C6H5, CH3, and H], have been prepared. They are shown to have the geometry with coordination by the pyridyl nitrogen and carbonyl oxygen atoms of the ylide ligands and to exhibit intramolecular rearrangement of coordinated COD in chloroform, methanol, and dimethyl sulphoxide based on IR and 1H NMR spectroscopies. Although the ylides have exhibited fluorescence bands due to an intramolecular charge-transfer transition and phosphorescence bands due to a carbonyl 3(n?π*) transition, the complexes have given emission bands due to the metal-to-ylide ligand charge-transfer transition. A.single crystal X-ray crystal structure has been determined for [Rh(COD)(C5H4NC(O)C?H+C5H4CH3-4)]ClO4. The crystals are monoclinic, space group P21/n with cell dimensions a = 14.887(3), b = 20.274(4), c = 6.966(1) Å, β = 96.13(1)°, and Z = 4. The structure has been refined by a block-diagonal least-squares method to final R = 0.060 for 2997 independent reflections with |Fo| > 3σ(F). The ylide carbon-pyridinium nitrogen bond distance is 1.420(10) Å. The bonded distances from rhodium to the midpoints of the double bonds of COD are 1.982(11) and 2.014(12) Å. 相似文献
60.